Registered Quality System ISO9001
Taizhou,Zhejiang,China
Material Safety Data Sheet
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Chemical Product and Company Identification
Trade Name: Super Glue
Product Identifier: Cyanoacrylate Adhesive
Manufacturer Information
MSDS Prepared by:
Jiaojiang Shundebao Industry & Trade Co.,Ltd.
No.117-7 Xingxing Avenue,Taizhou,Zhejiang,China
For addition health,safety or regulatory information,call +86-576-8011306
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Composition,Information on Ingredients
CAS No. Chemical Name Percentage by Weight ACGIH TWA Osha Pel Osha Stel
7085-85-0 ethyl-2-cyanoacrylate 60-100 n/e n/e n/e
9011-14-7 poly (methyl methacrylate) 10-30 n/e n/e n/e
123-31-9 hydroquinone 0-1 2mg/m3 2mg/m3 n/e
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Hazards Identification
3.1 Emergency Overview
Appearance : Colorless liquid
Odor : Irritating
CAUTION!
May become unstable at high temperatures or may react with water.May be harmful if inhaled. May cause irritation of nose,throat and lungs.
Bonds skin instantly. Causes skin irritation.
Bonds eyelids instantly. Causes eye irritation.
HMIS Rating
HEALTH = 1 (moderate)
FLAMMABILITY = 2 (moderate)
REACTIVITY = 1 (slight)
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Potential Health Effects
Immediate Hazards
INGESTION: No hazards known to company.
INHALATION: May be harmful if inhaled.Liquid or vapor may cause irritation of nose, throat and lungs.
SKIN: Bonds skin instantly. Causes irritation.
EYES: Bonds eyelids instantly. Irritates eyes,causes tearing from eye irritation.
4. First Aid Measures
INGESTION: If accidentally swallowed, dilute by drinking large quantities of water.Immediately contact poison control center or hospital emergency room for any other additional treatment directions.
INHALATION: If inhaled, remove to fresh air. If not breathing,give artificial respiration,
preferably mouth-to-mouth.Call a physician.
SKIN: If skin bonding occurs, soak in nail polish remover or acetone and carefully peel or
roll skin apart (do not pull).
EYES: If eye contact occurs, hold eyelid open and rinse thoroughly but gently with only
water for 15 minutes and GET MEDICAL ATTENTION. Do not use any solvents to
flush the eye and its surroundings. Liquid glue will sting eye
temporarily. Solidified glue may irritate eye like a grain of sand and should be
treated by an eye doctor.
5. Fire Fighting Measures
Autoignition Temperature: n/e
Upper/Lower Flammable Limits: Not available
Up/Lower Explosive Limits, % by Vol: Not available
Flash Point: 83 deg C (CC)
Keep away from heat and flame.
In case of fire, use water spray, dry chemical, foam or CO2. Use water to keep fire-expose containers cool.
6. Accidental Release Measures
Eliminate all ignition sources. Soak up with absorbent material and remove to a chemical disposal area. Prevent entry into natural bodies of water.
7. Handling and Storage
7.1 Handling
Handle in accordance with good industrial hygiene and safety practices. These practices include avoiding unnecessary exposure and removal of the material from eyes, skin and clothing.Wash thoroughly after handling. Always use appropriate Personal Protective Equipment (PPE).
INHALATION: Avoid breathing vapor. Use with adequate ventilation.
SKIN: Avoid contact with skin and clothing.
EYES: Avoid contact with eyes.
7.2 Storage
Keep away from amines.
Store in cool, dry area away from sun and heat.
Keep containers tightly closed.
Exposure to small amounts of moisture, even moisture in air, causespolymerization and renders the product unusable.
Keep away from heat, sparks, flame and other ignition sources.
8. Exposure Controls/Personal Protection
8.1 Exposure Controls
ENGINEERING CONTROLS: The following exposure control techniques may be used to effectively minimize employee exposure: local exhaust ventilation, enclosed system design, process isolation and remote control in combination with appropriate use of personal protective equipment and prudent work practices.These techniques may not necessarily address all issues pertaining to your operations. We, therefore, recommend that you consult with experts of your choice to determine whether or not your programs are adequate. If airborne contaminants are generated when the material is heated or handled, sufficient ventilation in volume and air flow patterns should be provided to keep air contaminant concentration levels below acceptable criteria.
8.2 Personal Protection
Where air contaminants can exceed acceptable criteria, use NIOSH/MSHA approved
respiratory protection equipment. Respirators should be selected based on the form and
concentration of contaminants in air in accordance with OSHA laws and regulations or other
applicable standards or guidelines, including ANSI standards regarding respiratory
protection.Use goggles if contact is likely.Wear impervious gloves as required to prevent
skin contact.
8.3 Exposure Guidelines
Ethyl 2-Cyanoacrylate 7085-85-0
ACGIH TLV: 2mg/m³ TWA
OSHA PEL: n/e
9. Physical and Chemical Properties
Percent Volatiles Not determined
pH @ 25 C Not available
Specific Gravity 1.05
Appearance Colorless liquid
Autoignition Temperature n/e
Boiling Point 62 deg C (5 mm Hg)
Vapor Density (Air=1) > 1
Vapor Pressure, mm Hg @ 20 C 0.13 (@ 20 deg C)
Evaporation Rate (Butyl Acetate=1) < 1
Upper/Lower Flammable Limits Not available
Up/Lower Explosive Limits, % by Vol Not available
Flash Point 83 deg C
Freezing Point < -20 deg C
Odor Irritating
Odor Threshold, ppm Not available
Solubility in Water Negligible
Coefficient of Water/Oil Distrib. Not applicable
10. Stability and Reactivity
Normally stable, but may become unstable at high temperatures or may react with water.
Conditions to Avoid: Exposure to heat, flame and incompatibles.
Incompatibilities: Water, alcohols, amines, bases and direct UV.
Decomposition products may include: Oxides of carbon.
Hazardous polymerization: Will not occur.
Other Hazards: None known to company.
11. Toxicological Information
See Section 3 Hazards Identification information.
Ethyl 2-Cyanoacrylate 7085-85-0
LC50: Not available
LD50: Not available
12. Ecological Information
Not determined.
13. Disposal Considerations
Recover free liquid. Absorb residue and dispose of according to local, state/provincial, and
federal requirements. Empty container: May contain explosive vapors. DO NOT cut,
puncture or weld on or nearby.
14. Transport Information
Ground: Not regulated
Air: Not regulated
Sea: Not regulated
15. Regulations Information
None
16. Other Information
Definitions: n/a=not applicable , n/e=not established
Disclaimer
SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE
PRODUCT OR THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE,
except that the product shall conform to contracted specifications, and that the product
does not infringe any valid United States or Canadian patent. No claim of any kind shall be
greater in amount than the purchase price of the quantity of product in respect of which
damages are claimed. In no event shall Seller be liable for incidental or consequential
damages, whether Buyer's claim is based on contract, breach of warranty, negligence or
otherwise.
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